The λ-transition of elemental sulfur is an endothermic process which is clearly visible in a DSC thermogram [11]. In particular, the DSC thermogram of elemental sulfur contains three endothermic signals: (1) the α → β transition of the sulfur crystals at 98°C, (2) the melting of the β-crystals at 116°C, and

(3) the λ-transition at 160°C (see Figure 3 (thermogram a) and Table 1). Figure 3 DSC thermograms of the S/GNP system. First (thermogram a) and second (thermogram b) heating run. Table 1 Thermodynamic properties of the S/GNP system obtained by DSC Selleck Blasticidin S T α → β ΔH α → β T β ΔH β T λ ΔH λ (°C) (J/g) (°C) (J/g) (°C) (J/g) 98 1.08 116 12.5 160 1.10 The isothermal annealing of the reactive sulfur/GNP system at temperatures higher than 160°C allows a more or less complete conversion of polysulfur bridges (C-S8-C) to Epoxomicin research buy monosulfur bridges (C-S-C) which are sort of electrical connections between the graphene planes because

conjugation is possible through the sulfur atom. When the GNP-based aerogels are devoted to electrical applications MK 2206 (e.g., electrodes for batteries and supercapacitors, electrolysis cells, etc.), such type of chemical cross-linking results are extremely convenient. The λ-transition is characterized by a clearly visible endothermic signal (the enthalpy change is 1.10 J/g), and it can be detected also in the DSC analysis of S/GNP mixtures (see Figure 3 (thermograms a and b)). Consequently, important information on the chemical interaction between sulfur and GNP can be obtained by DSC analysis. In particular, the change of the S-S bond concentration (i.e., the [S-S]/[S-S]0 value) can be calculated by analyzing the change in the enthalpy variation of the λ-transition signal. In particular, the thermal treatment of the S/GNP systems significantly modifies the DSC Carnitine dehydrogenase thermogram: the melting peak of the β-sulfur at 116°C disappears, and the λ-transition peak results strongly decreased

because the [S-S] is proportional to ΔH of the λ-transition. Such decrease of the λ-transition peak depends on time and temperature of the thermal annealing treatment. The fraction of reacted S-S bonds (α) is given by the following expression: (1) The temporal evolution of α at two different temperatures (300°C and 350°C) is shown in Figure 4. As visible, the experimental data are well described by an exponential recovery function (i.e., α = a − b × e −kt ). Figure 4 Behavior of the reacted S-S bond fraction with time. The experimental data points have been fitted by the exponential recovery law. Such experimental behavior of the reaction conversion suggests the following three-step reaction mechanism: The first reaction step involves the cleavage of the S-S bond with the formation of two sulfur radicals. This elemental reaction is reversible and has a slow specific rate. In the second elemental reaction, one of the two sulfur radicals is added to the carbon-carbon double bond with the formation of S-C bond and one carbon radical.