In a certain way this behavior was already expected, since guar gum does not form a gel in solution, being used as a thickener and stabilizer (Dziezak, 1991). On the other hand, as the concentration of the polyols increased

in the solution, the dependence of the G′ moduli on the frequency decreased, indicating greater structuring of the systems. The addition of polyols decreased the values for the phase angle as compared to the values obtained with the pure gum (G05 and G1), suggesting an increase in system elasticity, which behavior became less similar to that of a liquid and closer to that of a gel. The increase in system structuring was not proportional to the gum/polyol concentrations in the system. The solutions containing 0.5 g/100 g guar gum, pure or with 10 g/100 g of any of the polyols, presented δ > 1, which is characteristic of a dilute solution. With the addition of 40 g/100 g of any of the polyols, there

was a change to δ < 1, although Torin 1 the curves corresponding to the G05 systems were less dependent on frequency than those obtained with samples of G1. This is further evidence that the addition of 40 g/100 g polyol to solutions that already contain 1 g/100 g hydrocolloid creates a competitive effect for the water available in the system, resulting in less structured systems. The systems containing G1, pure and with polyols, showed liquid-like behavior at low frequencies (G″ > G′) and solid-liked behavior (G′ > G″) at higher frequencies, passing through a cross-over (G′ = G″). PD 332991 The cross-over moves to lower frequencies with increasing system concentration, indicating the behavior of a highly concentrated solution, as shown in Fig. 3 for solutions of guar gum added with maltitol. Chenlo et al. (2010) reported similar results to guar gum. Dynamic rheological measurements

were made by Evageliou, Kasapis, and Hember (1998), in systems composed of 0.5 g/100 g k-carrageen and high glucose syrup concentrations at a temperature of 5 °C, and the addition of 60 g/100 g glucose syrup resulted in an increase in system firmness. Doyle, Giannouli, Martin, Brooks, and Morris (2006), investigated the effect of high sorbitol concentrations (40–60 g/100 g) in the cryo-gelatinization of galactomannan (1 g/100 g). The gel strength showed an increase and subsequent reduction Non-specific serine/threonine protein kinase with increasing polyol concentration, the maximum strength being attained with 50 g/100 g sorbitol. Comparing Fig. 2a and b, it can be seen that the values reached for G′ were slightly higher for maltitol than for sorbitol. The systems containing xylitol presented results very similar to those obtained with sorbitol, the corresponding data being shown in Fig. 4, which also shows the effect of freezing/thawing on the solutions. The dependence of G′ and G″ on the frequency can be described by a power law-type equation, as shown in equations (3) and (4) ( Kim & Yoo, 2006; Rao, 1999; Wang et al.